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Hollow Giant Polyoxometalate Oxidation Shell Encapsulating Molecular Reduction Core for Unprecedented Photoredox Cascade Conversion Delving into Different Roles of Covalent Organic Frameworks in Zinc-Ion Batteries and Zinc-Air Batteries: A State-of-Art Review Charge-Transport Divergence in Ultrastable Heterometal-Oxo Clusters Exerting Significant Effect on Photoreactivity Multifunctional Engineering and Active Sites Regulation of Covalent Organic Frameworks for Efficient Electrocatalytic Acetylene Hydrogenation to Ethylene In situ Doping Coupling With Vacancy Regulation Induced Strong Metal-Support Interaction in Ni/CaTiO3 to Boost Supercharged Photothermal CO2 Methanation Crystal-Facet-Controlled Internal Electric Field in MOF/COF Heterojunction towards Efficient Photocatalytic Overall Water Splitting Hydrogen-localization Transfer Regulation in 3D COFs Enhances Photocatalytic Acetylene Semi-hydrogenation to Ethylene Subtle Tuning of Micro-Environment in COFs Nanoribbons Actuates Low Electricity-Consumption Photo-Assisted Co-Electrolysis of Methanol and CO2 Subtle Tuning of Catalytic Well Effect in Phthalocyanine Covalent Organic Frameworks for Selective CO2 Electroreduction into C2H4 Interweavable Metalloporphyrin-based Fibers for Indirect Electrocatalysis Solid‐Liquid‐Gas Three‐Phase Indirect Electrolysis Enabled by Affinity Auxiliary Imparted Covalent Organic Frameworks |